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  • Title: Multicomponent access to indolo[3,3a-c]isoquinolin-3,6-diones: formal synthesis of (±)-plicamine.
    Author: Mijangos MV, Miranda LD.
    Journal: Org Biomol Chem; 2016 Apr 12; 14(15):3677-80. PubMed ID: 26996434.
    Abstract:
    The complete tetracyclic core structure of plicamine, a novel Amaryllidaceae-type alkaloid, was expeditously prepared by a Ugi four-component condensation reaction, followed by a one-pot sequential phenolic oxidation and intramolecular coupling process. The employment of this strategy resulted in a rapid, formal synthesis of (±)-plicamine.
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