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  • Title: Synthesis of the (9R,13R)-isomer of LDS1, a flower-inducing oxylipin isolated from Lemna paucicostata.
    Author: Takayasu Y, Ogura Y, Towada R, Kuwahara S.
    Journal: Biosci Biotechnol Biochem; 2016 Aug; 80(8):1459-63. PubMed ID: 27023212.
    Abstract:
    The first synthesis of the (9R,13R)-stereoisomer of LDS1, a flower-inducing oxylipin isolated from Lemna paucicostata, has been achieved from a known allylic alcohol by a seven-step sequence that involves the Horner-Wadsworth-Emmons olefination to construct its full carbon framework and an enzymatic hydrolysis of a penultimate methyl ester intermediate to provide the target molecule.
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