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  • Title: Graphene functionalized with poly(vinyl alcohol) as a Pickering stabilizer for suspension polymerization of poly(methyl methacrylate).
    Author: Erdenedelger G, Dao TD, Jeong HM.
    Journal: J Colloid Interface Sci; 2016 Aug 15; 476():47-54. PubMed ID: 27187559.
    Abstract:
    Two types of thermally reduced graphenes (TRGs) having different lateral sizes were non-covalently modified with poly(vinyl alcohol) to endow water-dispersibility. The modified TRGs were examined as Pickering stabilizers for the suspension polymerization of methyl methacrylate (MMA). They were effective graphene-based Pickering stabilizers for the system with almost all of the polymerized composite microparticles having a regular spherical shape. The particle size of the composite microparticles was tunable by the size or the amount of modified TRG used as stabilizer. The almost perfect core-shell structure of the composite microparticles effectively enhanced the thermal stability of the core PMMA. In addition, when the core-shell microparticles were compression molded into a monolith, the obtained composite exhibited an ultra-low percolation threshold of electrical conductivity of around 0.04vol%.
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