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  • Title: Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters.
    Author: Zeng XP, Cao ZY, Wang YH, Zhou F, Zhou J.
    Journal: Chem Rev; 2016 Jun 22; 116(12):7330-96. PubMed ID: 27251100.
    Abstract:
    This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and meso-compounds, highlights the power and potential of this strategy in the total synthesis of natural products and biologically active compounds, and outlines the synthetic opportunities still available.
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