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  • Title: (Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol.
    Author: Ballistreri FP, Gangemi CM, Pappalardo A, Tomaselli GA, Toscano RM, Trusso Sfrazzetto G.
    Journal: Int J Mol Sci; 2016 Jul 12; 17(7):. PubMed ID: 27420047.
    Abstract:
    Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H₂O employing H₂O₂ as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).
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