These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Concentration-dependent studies of Nd3+ -doped zinc phosphate glasses for NIR photoluminescence at 1.05 μm.
    Author: Reddy Prasad V, Seshadri M, Babu S, Ratnakaram YC.
    Journal: Luminescence; 2017 May; 32(3):443-451. PubMed ID: 27546167.
    Abstract:
    Nd3+ -doped lead-free zinc phosphate glasses with the chemical compositions (60-x) NH4 H2 PO4  + 20ZnO + 10BaF2  + 10NaF + xNd2 O3 (where x = 0.5, 1.0, 1.5, 2.0 and 2.5 mol%) were prepared using a melt quenching technique. Vibrational bands were assigned and clearly elucidated by Raman spectral profiles for all the glass samples. Judd-Ofelt (J-O) intensity parameters (Ωλ : λ = 2, 4, 6) were obtained from the spectral intensities of different absorption bands of Nd3+ ions. Radiative properties such as radiative transition probabilities (AR ), radiative lifetimes (τR ) and branching ratios (βR ) for different excited states were calculated using J-O parameters. The near infrared (NIR) photoluminescence spectra exhibited three emission bands (4 F3/2 level to 4 I13/2 , 4 I11/2 and 4 I9/2 states) for all the concentrations of Nd3+ ions. Various luminescence properties were studied by varying the Nd3+ concentration for the three spectral profiles. Fluorescence decay curves of the 4 F3/2 level were recorded. The energy transfer mechanism that leads to quenching of the 4 F3/2 state lifetimes was discussed at higher concentration of Nd3+ ions. These glasses are suggested as suitable hosts to produce efficient lasing action in NIR region at 1.05 μm.
    [Abstract] [Full Text] [Related] [New Search]