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  • Title: Bipyridyltriazolium Chlorobismuthate with Thermo-/Photochromic and Photoluminescent Switching Behaviors Based on ET and CT†.
    Author: Li G, Hao P, Shen J, Yu T, Li H, Fu Y.
    Journal: Inorg Chem; 2016 Nov 07; 55(21):11342-11347. PubMed ID: 27768286.
    Abstract:
    Matched with 3,5-bis(pyridine-2-yl)-1,2,4-triazole (2-bpt), a new electron donor-acceptor-based chlorobismuthate(III) hybrid, [2-bpt]2[Bi2Cl10(H2O)]·5H2O was prepared solvothermally and characterized. The title compound (hydrated form) and its dehydrated form exhibit photo- and thermo-induced intermolecular electron transfer (ET), which correspond to dual ET photo/thermochromism for hydrated form, charge transfer thermochromism during dehydration, and simultaneously photoluminescent responses, respectively.
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