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  • Title: Boron Trifluoride Gas Adsorption in Metal-Organic Frameworks.
    Author: Siu PW, Siegfried JP, Weston MH, Fuller PE, Morris W, Murdock CR, Hoover WJ, Richardson RK, Rodriguez S, Farha OK.
    Journal: Inorg Chem; 2016 Dec 05; 55(23):12110-12113. PubMed ID: 27934404.
    Abstract:
    Coordinatively unsaturated metal-organic frameworks (MOFs) were studied for boron trifluoride (BF3) sorption. MOF-74-Mg, MOF-74-Mn, and MOF-74-Co show high initial uptake (below 6.7 × 10-3 bar) with negligible deliverable capacity. The BF3 isotherm of MOF-74-Cu exhibits gradual uptake up to 0.9 bar and has a deliverable gravimetric capacity that is more than 100% higher than activated carbon. Two other Cu2+ MOFs, MOF-505 and HKUST-1, have slightly lower deliverable capacities compared to MOF-74-Cu.
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