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  • Title: Efficient Synthetic Routes to (±)-Hippolachnin A, (±)-Gracilioethers E and F and the Alleged Structure of (±)-Gracilioether I.
    Author: Xu ZJ, Wu Y.
    Journal: Chemistry; 2017 Feb 10; 23(9):2026-2030. PubMed ID: 27957781.
    Abstract:
    Two monocyclic members in the gracilioether family were synthesized in only three steps. The monocyclic products were further elaborated into advanced precursors to hippolachnin A and gracilioether E, respectively. Gracilioether F and the alleged structure for gracilioether I were also synthesized using a late-stage C(sp3 )-H thermo-oxidation.
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