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  • Title: Palladium-catalyzed carbonylative synthesis of isocoumarins and phthalides by using phenyl formate as a carbon monoxide source.
    Author: Yuan Q, Chen ZB, Zhang FL, Zhu YM.
    Journal: Org Biomol Chem; 2017 Feb 21; 15(7):1628-1635. PubMed ID: 28120978.
    Abstract:
    A simple and efficient palladium-catalyzed intramolecular carbonylative synthesis of isocoumarins and phthalides from the easily available starting materials by employing phenyl formate as a CO surrogate has been achieved. The approach affords target compounds in good to excellent yields with the advantages of lower toxicity, milder conditions, easy operation and wide functional group tolerance.
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