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  • Title: An unexpected pathway for hydrodesulfurization of gazole over a CoMoS active phase supported on a mesoporous TiO2 catalyst.
    Author: Naboulsi I, Felipe Linares Aponte C, Lebeau B, Brunet S, Michelin L, Bonne M, Blin JL.
    Journal: Chem Commun (Camb); 2017 Feb 28; 53(18):2717-2720. PubMed ID: 28197588.
    Abstract:
    Using dual mesoporous titania as a support, due to the presence of intrinsic Brönsted acid sites, the main approach to 4,6-dimethylbenzothiophene (46DMDBT) hydrodesulfurization (HDS) becomes the direct desulfurization (DDS) route through isomerization and dismutation reactions, instead of the hydrogenation (HYD) pathway usually observed with a conventional promoted (by Ni or Co) MoS2/Al2O3 catalyst.
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