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  • Title: Atomically-resolved edge states on surface-nanotemplated graphene explored at room temperature.
    Author: Merino P, Santos H, Pinardi AL, Chico L, Martin-Gago JA.
    Journal: Nanoscale; 2017 Mar 17; 9(11):3905-3911. PubMed ID: 28261718.
    Abstract:
    Graphene edges present localized electronic states strongly depending on their shape, size and border configuration. Chiral- or zigzag-ended graphene nanostructures develop spatially and spectrally localized edge states around the Fermi level; however, atomic scale investigations of such graphene terminations and their related electronic states are very challenging and many of their properties remain unexplored. Here we present a combined experimental and theoretical study on graphene stripes showing strong metallic edge states at room temperature. By means of scanning tunneling microscopy, we demonstrate the use of vicinal Pt(111) as a template for the growth of graphene stripes and characterize their electronic structure. We find the formation of a sublattice localized electronic state confined on the free-standing edges of the graphene ribbons at energies close to the Fermi level. These experimental results are reproduced and understood with tight-binding and ab initio calculations. Our results provide a new way of synthesizing wide graphene stripes with zigzag edge termination and open new prospects in the study of valley and spin phenomena at their interfaces.
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