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  • Title: Colorimetric and fluorescent chemosensor for highly selective and sensitive relay detection of Cu2+ and H2PO4- in aqueous media.
    Author: Su JX, Wang XT, Chang J, Wu GY, Wang HM, Yao H, Lin Q, Zhang YM, Wei TB.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2017 Jul 05; 182():67-72. PubMed ID: 28395227.
    Abstract:
    In this manuscript, a new colorimetric and fluorescent chemosensor (T) was designed and synthesized, it could successively detect Cu2+ and H2PO4- in DMSO/H2O (v/v=9:1, pH=7.2) buffer solution with high selectivity and sensitivity. When added Cu2+ ions into the solution of T, it showed a color changes from yellow to colorless, meanwhile, the green fluorescence of sensor T quenched. This recognition behavior was not affected in the presence of other cations, including Hg2+, Ag+, Ca2+, Co2+, Ni2+, Cd2+, Pb2+, Zn2+, Cr3+, and Mg2+ ions. More interestingly, the Cu2+ ions contain sensor T solution could recover the color and fluorescence upon the addition of H2PO4- anions in the same medium. And other surveyed anions (including F-, Cl-, Br-, I-, AcO-, HSO4-, ClO4-, CN- and SCN-) had nearly no influence on the recognition behavior. The detection limits of T to Cu2+ and T-Cu2+ to H2PO4- were evaluated to be 1.609×10-8M and 0.994×10-7M, respectively. In addition, the sensor T also could be served as a recyclable component and the logic gate output was also defined in sensing materials. The test strips based on sensor T were fabricated, which acted as a convenient and efficient Cu2+ and H2PO4- test kits.
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