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  • Title: Construction of valence bond structures for {FeNO}7 nitrosyl heme and non-heme complexes.
    Author: Harcourt RD.
    Journal: Nitric Oxide; 2017 Sep 30; 69():51-55. PubMed ID: 28478280.
    Abstract:
    For {FeNO}7 nitrosyl heme and non-heme complexes, with 17 valence shell electrons, FeIINO, FeIINO* and FeIIINO- valence bond structures of the increased-valence type are generated primarily from Lewis valence bond structures by delocalizing non-bonding electrons into diatomic bonding molecular orbitals. Valence bond formulations for the reactions 2MbNO + 2H+ → 2metMb + N2O + H2O and cis MbNO + NO- + 2H+ → metMb + N2O + H2O are also presented.
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