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  • Title: Copper(i)-mediated carboamination of vinyl azides by aryldiazonium salts: synthesis of N2-substituted 1,2,3-triazoles.
    Author: Liu Z, Ji H, Gao W, Zhu G, Tong L, Lei F, Tang B.
    Journal: Chem Commun (Camb); 2017 Jun 06; 53(46):6259-6262. PubMed ID: 28541352.
    Abstract:
    A copper(i)-mediated carboamination cascade reaction between vinyl azides and aryldiazonium salts is described. Functionally diverse N2-substituted 1,2,3-triazoles were obtained in moderate to good yields through novel difunctionalization of vinyl azides by aryldiazonium salt sources. This method has a wide scope, good functional-group tolerance and insensitivity to an ambient atmosphere.
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