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  • Title: Total Synthesis of (±)-Waihoensene.
    Author: Lee H, Kang T, Lee HY.
    Journal: Angew Chem Int Ed Engl; 2017 Jul 03; 56(28):8254-8257. PubMed ID: 28544050.
    Abstract:
    The first total synthesis of waihoensene, a tetracyclic diterpene containing an angular triquinane and a six-membered ring, with four contiguous quaternary carbon atoms, was achieved through the tandem cycloaddition reaction of an allenyl diazo substrate containing a six-membered ring via trimethylenemethane (TMM) diyl intermediate.
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