These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: A Mononuclear Nonheme Iron(V)-Imido Complex.
    Author: Hong S, Sutherlin KD, Vardhaman AK, Yan JJ, Park S, Lee YM, Jang S, Lu X, Ohta T, Ogura T, Solomon EI, Nam W.
    Journal: J Am Chem Soc; 2017 Jul 05; 139(26):8800-8803. PubMed ID: 28628312.
    Abstract:
    Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]- (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) Å, and an Fe-N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.
    [Abstract] [Full Text] [Related] [New Search]