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  • Title: Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.
    Author: Fu GC.
    Journal: ACS Cent Sci; 2017 Jul 26; 3(7):692-700. PubMed ID: 28776010.
    Abstract:
    Classical methods for achieving nucleophilic substitutions of alkyl electrophiles (SN1 and SN2) have limited scope and are not generally amenable to enantioselective variants that employ readily available racemic electrophiles. Radical-based pathways catalyzed by chiral transition-metal complexes provide an attractive approach to addressing these limitations.
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