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  • Title: Gold(I)-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals.
    Author: Palo-Nieto C, Sau A, Galan MC.
    Journal: J Am Chem Soc; 2017 Oct 11; 139(40):14041-14044. PubMed ID: 28934850.
    Abstract:
    Au(I) in combination with AgOTf enables the unprecedented direct and α-stereoselective catalytic synthesis of deoxyglycosides from glycals. Mechanistic investigations suggest that the reaction proceeds via Au(I)-catalyzed hydrofunctionalization of the enol ether glycoside. The room temperature reaction is high yielding and amenable to a wide range of glycal donors and OH nucleophiles.
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