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  • Title: Chiral Organocatalyzed Intermolecular Rauhut-Currier Reaction of Nitroalkenes with Ethyl Allenoate.
    Author: Takizawa S, Sako M, Kishi K, Shigenobu M, Vo-Thanh G, Sasai H.
    Journal: Chem Pharm Bull (Tokyo); 2017; 65(11):997-999. PubMed ID: 29093299.
    Abstract:
    An enantioselective intermolecular Rauhut-Currier (RC) reaction of nitroalkenes with ethyl allenoate has been established with quinidine-derived β-isocupreidine. The present RC reaction afforded α-functionalized allenoates 3 in up to 94% yield with 59% enantiomeric excess (ee).
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