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  • Title: A set of biogenetically interesting polyhalogenated acetogenins from Ptilonia magellanica.
    Author: Gallardo AB, Cueto M, Díaz-Marrero AR, de la Rosa JM, Fajardo V, San-Martín A, Darias J.
    Journal: Phytochemistry; 2018 Jan; 145():111-120. PubMed ID: 29126019.
    Abstract:
    Ptilonines A-F, pyranosylmagellanicus D-E and magellenediol are previously undescribed acetogenins isolated from the red alga Ptilonia magellanica. Their structures were determined from spectroscopic evidence. The absolute configuration of the known pyranosylmagellanicus A, was established by derivatization with (R)- and (S)-α-methoxy -α-phenylacetic acids (MPA). Ptilonines exhibit an unusual halogenation pattern, that may confer evolutionary advantages to Ptilonia magellanica, for which a biogenetic origin is proposed. The antimicrobial effect of some of these compounds was evaluated.
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