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  • Title: Observation of A Raman mode splitting in few layer black phosphorus encapsulated with hexagonal boron nitride.
    Author: Urban JM, Baranowski M, Surrente A, Wlodarczyk D, Suchocki A, Long G, Wang Y, Klopotowski L, Wang N, Maude DK, Plochocka P.
    Journal: Nanoscale; 2017 Dec 14; 9(48):19298-19303. PubMed ID: 29192915.
    Abstract:
    We investigate the impact of encapsulation with hexagonal boron nitride (h-BN) on the Raman spectrum of few layer black phosphorus. The encapsulation results in a significant reduction of the line width of the Raman modes of black phosphorus, due to a reduced phonon scattering rate. We observe a so far elusive peak in the Raman spectra ∼4 cm-1 above the A mode in trilayer and thicker flakes, which had not been observed experimentally. The newly observed mode originates from the strong black phosphorus inter-layer interaction, which induces a hardening of the surface atom vibration with respect to the corresponding modes of the inner layers. The observation of this mode suggests a significant impact of h-BN encapsulation on the properties of black phosphorus and can serve as an indicator of the quality of its surface.
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