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  • Title: Synthesis of hierarchical Co3O4@NiO core-shell nanotubes with a synergistic catalytic activity for peroxidase mimicking and colorimetric detection of dopamine.
    Author: Zhu Y, Yang Z, Chi M, Li M, Wang C, Lu X.
    Journal: Talanta; 2018 May 01; 181():431-439. PubMed ID: 29426536.
    Abstract:
    Fabrication of core-shell nanostructured catalyst is a promising way for tuning its catalytic performance due to the highly active interface and rich redox properties. In this work, hierarchical Co3O4@NiO core-shell nanotubes are fabricated by the deposition of NiO shells via a chemical bath treatment using electrospun Co-C composite nanofibers as templates, followed by a calcination process in air. The as-prepared Co3O4@NiO core-shell nanotubes exhibit a uniform and novel hollow structure with Co3O4 nanoparticles attached to the inner wall of NiO nanotubes and excellent catalytic activity toward the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H2O2. Due to the synergistic effect, the peroxidase-like activity of the Co3O4@NiO core-shell nanotubes is much higher than that of individual Co3O4 and NiO components. Owing to the superior peroxidase-like activity, a simple and rapid colorimetric approach for the detection of dopamine with a detection limit of 1.21µM and excellent selectivity has been developed. It is anticipated that the prepared Co3O4@NiO core-shell nanotubes are promising materials applied for biomedical analysis and environmental monitoring.
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