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  • Title: Pd(II)/PhI(OAc)2 promoted direct cross coupling of glucals with aromatic acids.
    Author: Begum Z, Shankar G, Sirisha K, Reddy BVS.
    Journal: Carbohydr Res; 2018 May 22; 461():1-3. PubMed ID: 29549748.
    Abstract:
    A highly efficient oxidative C2-aroyloxylation of D-glucal with aromatic carboxylic acids has been achieved for the first time using 5 mol% Pd(OAc)2 and 1 equiv of PhI(OAc)2 to produce C2-aroyloxyglycals in good yields. The use of excess of PhI(OAc)2 (2 equiv) provides C2-acyloxyglycal exclusively.
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