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  • Title: Residue dissipation and risk assessment of tebuconazole, thiophanate-methyl and its metabolite in table grape by liquid chromatography-tandem mass spectrometry.
    Author: Dong B, Yang Y, Pang N, Hu J.
    Journal: Food Chem; 2018 Sep 15; 260():66-72. PubMed ID: 29699683.
    Abstract:
    An efficient method was developed and validated for simultaneous determination of tebuconazole, thiophanate-methyl and its metabolite carbendazim in grape and soil using QuEChERS procedure and liquid chromatography-tandem mass spectrometry. The average recoveries of the method were 83.2%-105.4%, the limit of detection (LOD) ranged from 2.1 × 10-5 to 8.7 × 10-4 mg L-1, and the limit of quantitation (LOQ) was 0.1 mg kg-1. The field results showed that tebuconazole and thiophanate-methyl in soil and grape were rapidly dissipated with half-lives less than 24.7 days. The terminal residues of all analytes in grape were lower than the maximum residue limit (MRL) set by China (2 mg kg-1 for tebuconazole; 3 mg kg-1 for both thiophanate-methyl and carbendazim). Risk assessment showed that tebuconazole, thiophanate-methyl and its metabolite would be unlikely to cause health problems. However, carbendazim, the higher active metabolites of thiophanate-methyl, should receive more concerns.
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