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  • Title: Enantioselective analysis and degradation of isofenphos-methyl in vegetables by liquid chromatography-tandem mass spectrometry.
    Author: Wang L, Wang X, Di S, Qi P, Sun Y, Yang X, Zhao C, Wang X.
    Journal: Environ Sci Pollut Res Int; 2018 Jul; 25(19):18772-18780. PubMed ID: 29713973.
    Abstract:
    The enantioselective degradation of isofenphos-methyl in cowpea, cucumber, and pepper under field conditions was investigated to elucidate the enantioselective environmental behaviors of this pesticide. The concentrations of the enantiomers were determined by liquid chromatography-tandem mass spectrometry (LC-MS/MS). The degradation rates of isofenphos-methyl enantiomers were the fastest in cowpea, followed by cucumber and pepper, with half-lives ranging from 1.48 to 8.06 days. The enantioselective degradation of isofenphos-methyl was characterized by calculating and comparing the values of enantiomer fraction (EF) and enantiomeric selectivity (ES). The degradation rates and enantioselectivities of isofenphos-methyl were different for the three vegetables. (R)-(-)-isofenphos-methyl was degraded faster than (S)-(+)-isofenphos-methyl in cowpea and cucumber, whereas (S)-(+)-isofenphos-methyl underwent preferential degradation in pepper. These results could serve as a reference for the study of enantioselective behavior of isofenphos-methyl in plants and further food safety evaluation, where the enantiomeric differences should be considered in the risk assessment.
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