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  • Title: A metal-organic framework based on a custom-designed diisophthalate ligand exhibiting excellent hydrostability and highly selective adsorption of C2H2 and CO2 over CH4.
    Author: Wang Y, He M, Gao X, Li S, He Y.
    Journal: Dalton Trans; 2018 May 29; 47(21):7213-7221. PubMed ID: 29756153.
    Abstract:
    The ligand truncation strategy provides facile access to a wide variety of linkers for the construction of MOFs bearing diverse structures and intriguing properties. In this work, we employed this strategy to design and prepare a novel bent diisophthalate ligand, and used it to successfully construct a copper-based MOF ZJNU-51 with the formula of [Cu2L(H2O)2]·5DMF (H4L = 5,5'-(triphenylamine-4,4'-diyl) diisophthalic acid), which was thoroughly characterized by various techniques including FTIR, TGA, PXRD and single-crystal X-ray diffraction. ZJNU-51 is a two-fold interpenetrated network in which the single network consists of dicopper paddlewheel units connected by the organic ligands and contains open channels as well as six distinct types of metal-organic cages. Furthermore, gas adsorption properties with respect to C2H2, CO2, and CH4 were systematically investigated, demonstrating that ZJNU-51 is a highly promising material for C2H2/CH4 and CO2/CH4 separations. Specifically, the IAST adsorption selectivity at 298 K and 1 atm reaches 35.6 and 5.4 for the equimolar C2H2/CH4 and CO2/CH4 gas mixtures, respectively. More significantly, as revealed by PXRD and N2 adsorption measurements, ZJNU-51 exhibits excellent chemical stability, which lays a good foundation for its practical application.
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