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Title: PAH and PCB contamination in the sediments of the Venice Lagoon (Italy) before the installation of the MOSE flood defence works. Author: Cassin D, Dominik J, Botter M, Zonta R. Journal: Environ Sci Pollut Res Int; 2018 Sep; 25(25):24951-24964. PubMed ID: 29931647. Abstract: Contamination from polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in the shallow water areas of the Venice Lagoon (415 km2) was investigated in the surface (0-5 cm) and sub-surface (5-10 cm) sediments by collecting cores from 380 sites. The concentrations of 14 PAHs (USEPA priority pollutants) and seven PCB indicator congeners were analysed with high-performance liquid chromatography (HPLC) and capillary gas chromatography (GC), respectively. PAH and PCB concentrations ranged from 2.75 to 9980 ng g-1 d.w. and from 0.01 to 60.1 ng g-1 d.w., respectively. Their concentrations never exceeded the probable effect level (PEL) stipulated in the respective quality guidelines. In addition, the average total PAH levels expressed as B[a]P toxicity equivalents (total TEQ) were lower in the sediments of the Venice Lagoon than in other literature-reported zones in the Mediterranean. PAH profiles and ratios showed that they originated not only largely from high-temperature pyrolytic processes attributable primarily to the burning of fossil fuels but also partly from petroleum spillage. Comparison of tetra-to-hepta PCB congeners enabled the PCB profiles observed in the lagoon environment to be characterised as Aroclor 1254 and 1260 (1:1). Compared to other marine coastal areas and harbours in the Mediterranean, the Venice Lagoon sediments showed a low mean value but a wide range of concentrations. The estimation of PAH and PCB inventories indicated the low contribution of atmospheric deposition relative to local sources.[Abstract] [Full Text] [Related] [New Search]