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  • Title: Quantum cascade laser based absorption spectroscopy for direct monitoring of atmospheric N2O isotopes.
    Author: Zhou S, Liu N, Zhang L, He T, Li J.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2018 Dec 05; 205():79-84. PubMed ID: 30015032.
    Abstract:
    A compact high-resolution spectroscopic sensor using a thermoelectrically (TE) cooled continuous-wave (CW) room temperature (RT) quantum cascade laser (QCL) operating at 4.6 μm, is employed for simultaneous detection of three main isotopic species (14N15N16O, 15N14N16O and 14N14N16O). To enable a high-precision analysis of N2O isotopic species at ambient mixing ratios, a liquid nitrogen-free preconcentration unit is built to trap and load atmospheric N2O. The absorption spectra of 14N15N16O, 15N14N16O, and 14N14N16O between 2188.6 cm-1 and 2189 cm-1 are measured, and the respective ratios of the rare to the abundant isotopologues abundances are demonstrated. Moreover, spectroscopic parameters of pressure-broadening coefficient for selected absorption lines have been determined, and a good agreement is obtained by comparing with HITRAN database.
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