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  • Title: Short Total Synthesis of Ajoene.
    Author: Silva F, Khokhar SS, Williams DM, Saunders R, Evans GJS, Graz M, Wirth T.
    Journal: Angew Chem Int Ed Engl; 2018 Sep 17; 57(38):12290-12293. PubMed ID: 30079981.
    Abstract:
    We describe a short total synthesis of ajoene, a major biologically active constituent of garlic. The instability of allicin as the only other known alternative starting material has led to the development of a reliable procedure for the synthesis of ajoene from simple building blocks that is also suitable for upscale operations.
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