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  • Title: A new two-dimensional CoII coordination polymer based on bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether and biphenyl-4,4'-diyldicarboxylic acid: synthesis, crystal structure and photocatalytic degradation activity.
    Author: Chen NN, Ni JL, Wang J.
    Journal: Acta Crystallogr C Struct Chem; 2018 Oct 01; 74(Pt 10):1123-1127. PubMed ID: 30284977.
    Abstract:
    A novel two-dimensional CoII coordination framework, namely poly[(μ2-biphenyl-4,4'-diyldicarboxylato-κ2O4:O4'){μ2-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl] ether-κ2N3:N3'}cobalt(II)], [Co(C14H8O4)(C20H18N4O)]n, has been prepared and characterized by IR, elemental analysis, thermal analysis and single-crystal X-ray diffraction. The crystal structure reveals that the compound has an achiral two-dimensional layered structure based on opposite-handed helical chains. In addition, it exhibits significant photocatalytic degradation activity for the degradation of methylene blue.
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