These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Determination of Enantiomeric Excess by Solid-Phase Extraction Using a Chiral Metal-Organic Framework as Sorbent.
    Author: Zhang JH, Tang B, Xie SM, Wang BJ, Zhang M, Chen XL, Zi M, Yuan LM.
    Journal: Molecules; 2018 Oct 29; 23(11):. PubMed ID: 30380604.
    Abstract:
    Metal-organic frameworks (MOFs) have recently attracted considerable attention because of their fascinating structures and intriguing potential applications in diverse areas. In this study, we developed a novel method for determination of enantiomeric excess (ee) of (±)-1,1'-bi-2-naphthol by solid-phase extraction (SPE) using a chiral MOF, [Co(l-tyr)]n(l-tyrCo), as sorbent. After optimization of the experimental conditions, a good linear relationship between the ee and the absorbance of the eluate (R² = 0.9984) was obtained and the standard curve was established at the concentration of 3 mmol L-¹. The ee values of (±)-1,1'-bi-2-naphthol samples can be rapidly calculated using the standard curve after determination of the absorbance of the eluate. The method showed good accuracy, with an average error of 2.26%, and is promising for ee analysis.
    [Abstract] [Full Text] [Related] [New Search]