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  • Title: Fabrication of metal-organic frameworks@cellulose aerogels composite materials for removal of heavy metal ions in water.
    Author: Lei C, Gao J, Ren W, Xie Y, Abdalkarim SYH, Wang S, Ni Q, Yao J.
    Journal: Carbohydr Polym; 2019 Feb 01; 205():35-41. PubMed ID: 30446114.
    Abstract:
    In the present work, we develop novel method of loading metal-organic frameworks (UiO-66 and UiO-66-NH2) on the flexible cellulose aerogels as metal-organic frameworks@cellulose aerogels composite materials by using in situ growth procedure at room temperature. The as prepared metal-organic frameworks@cellulose aerogels composite materials were well characterized via SEM, XRD, atomic absorption spectrometer, and TG analysis, besides the adsorption of Pb2+ and Cu2+ in metal-organic frameworks@cellulose aerogels composite materials was investigated. The amount of metal ions adsorbed by metal-organic frameworks@cellulose aerogels composite materials is equal to the sum of metal-organic frameworks and cellulose aerogels, indicating that the metal-organic frameworks are not blocked after cellulose aerogels growth and still have adsorption properties. It was found that metal-organic frameworks@cellulose aerogels composite materials can be recycled to adsorb Pb2+ and Cu2+ in water after simple cleaning. The equilibrium adsorption capacity of Pb2+ adsorbed by UiO-66-NH2@CA was 89.40 mg g-1, and can be easily reused for more than 5 cycles without significant decrease in performance. Moreover, the maximum decomposition temperature (Tmax) of UiO-66-NH2@CA was increased by 62.1℃. This result suggested that such metal-organic frameworks@cellulose aerogels composite materials could adsorb heavy metal ions in water could by avoiding secondary pollution and show great potential in water treatment.
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