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  • Title: A novel aluminum-sensitive fluorescent chemosensor based on 4-aminoantipyrine: An experimental and theoretical study.
    Author: Alyaninezhad Z, Bekhradnia A, Feizi N, Arshadi S, Zibandeh M.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2019 Apr 05; 212():32-41. PubMed ID: 30594851.
    Abstract:
    A practical and an efficient Schiff base fluorescent chemosensor, salicylidene-4-aminoantipyrinyl-4-aminophenol (A2) has been synthesized through the condensation procedure of 1-phenyl-2,3-dimethyl-4-(N-2-hydroxybenzylidene)-3-pyrazoline-5-one and 4-aminophenol. Compound A2 has displayed a considerable fluorescence enhancement with high selectivity and sensitivity toward Al3+ ion and exhibited an emission band at 484 nm, which contained a low detection limit (LOD) of 1.06 × 10-7 M. In accordance to the experimental study, DFT, TDDFT calculations, and the enhancement of fluorescence intensity might be attributed to the inhibition of Photoinduced Electron Transfer (PET) along with the Excited-State Intramolecular Proton Transfer (ESIPT). As it has been specified by Job's plot and DFT calculations, the binding stoichiometries of A2 with Al3+ are 1:1, while the association constant (Ka) of Al3+ has been calculated and observed to be 2.67 × × 105 M-1. Furthermore, the binding behavior and sensing mechanism of A2 with Al3+ have been confirmed through the experiments of 1H NMR titration.
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