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  • Title: Novel sequential separation and determination of a quaternary mixture of fungicides by using an automatic fluorimetric optosensor.
    Author: Delgado-Blanca I, Ruiz-Medina A, Ortega-Barrales P.
    Journal: Food Addit Contam Part A Chem Anal Control Expo Risk Assess; 2019 Feb; 36(2):278-288. PubMed ID: 30650038.
    Abstract:
    A versatile flow-through multi-optosensor is proposed for the separation and spectrofluorimetric determination of mixtures of four widely used pesticides: carbendazim, thiabendazole, carbaryl and o-phenylphenol at µg g-1 levels in fruits. The flow system is based on the online pre-concentration and separation of the pesticides on a solid sensing microzone, followed by the sequential measurement of their native fluorescence. The separation of the pesticides takes place on a solid support located in the same flow cell, on which analytes are temporarily immobilized and separated from the matrix due to their different retention/desorption kinetics when they interact with the C18 silica gel microbeads. Suitable analytical parameters were obtained for the selected analytes, with method detection and quantification limits ranging between 0.1-0.5 and 0.2-1.6 µg g-1, respectively. These values comply with the maximum residue limits (MRLs) established by the Codex Alimentarius for these commodities; in addition, carbendazim, thiabendazole and ortho-phenylphenol comply with the MRLs of The European Union. The developed method was applied to the analysis of citrus fruits by performing recovery studies. Recoveries between 85% and 115% were obtained in all cases, and the results were confirmed by a liquid chromatography-mass spectrometry reference method.
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