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  • Title: Iminyl Radical-Triggered Intermolecular Distal C(sp3)-H Heteroarylation via 1,5-Hydrogen-Atom Transfer (HAT) Cascade.
    Author: Gu YR, Duan XH, Chen L, Ma ZY, Gao P, Guo LN.
    Journal: Org Lett; 2019 Feb 15; 21(4):917-920. PubMed ID: 30688076.
    Abstract:
    An efficient iron-catalyzed intermolecular remote C(sp3)-H heteroarylation of alkyl ketones has been developed via an iminyl radical-triggered 1,5-hydrogen-atom transfer (HAT) cascade. This protocol was amenable to a wide variety of alkyl ketones and heteroaryls, thus providing a straightforward method for the late-stage functionalization of alkylketones and heteroaryls.
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