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  • Title: Asymmetric Total Synthesis of Fawcettimine-Type Lycopodium Alkaloid, Lycopoclavamine-A.
    Author: Kaneko H, Takahashi S, Kogure N, Kitajima M, Takayama H.
    Journal: J Org Chem; 2019 May 03; 84(9):5645-5654. PubMed ID: 30919625.
    Abstract:
    An asymmetric total synthesis of lycopoclavamine-A (1), a structurally unique fawcettimine-type Lycopodium alkaloid, was achieved via a stereoselective Pauson-Khand reaction and a stereoselective conjugate addition to construct a quaternary carbon center at C-12.
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