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  • Title: Deaminative Reductive Arylation Enabled by Nickel/Photoredox Dual Catalysis.
    Author: Yi J, Badir SO, Kammer LM, Ribagorda M, Molander GA.
    Journal: Org Lett; 2019 May 03; 21(9):3346-3351. PubMed ID: 30993991.
    Abstract:
    Described is a cross-electrophilic, deaminative coupling strategy harnessing Katritzky salts as a new species of electrophile in Ni/photoredox dual catalytic reductive cross-coupling reactions. Distinguishing features of this arylation protocol include its mild reaction conditions, high chemoselectivity, and adaptability to a variety of complex substrates [i.e., pyridinium salts derived from amines and partners derived from (hetero)aryl bromides].
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