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  • Title: Effective mineralization of quinoline and bio-treated coking wastewater by catalytic ozonation using CuFe2O4/Sepiolite catalyst: Efficiency and mechanism.
    Author: Liu D, Wang C, Song Y, Wei Y, He L, Lan B, He X, Wang J.
    Journal: Chemosphere; 2019 Jul; 227():647-656. PubMed ID: 31015085.
    Abstract:
    In this study, CuFe2O4 nanocomposite loaded on natural sepiolite (CuFe2O4/SEP) was prepared by the citrate sol-gel method. CuFe2O4/SEP was characterized by X-ray diffraction, Brunauer-Emmett-Teller adsorption analysis, scanning electron microscopy, and energy dispersive spectroscopy. The CuFe2O4/SEP composite was stable and showed an excellent catalytic activity for ozonation. The efficiency of quinoline mineralization in the catalytic ozonation with CuFe2O4/SEP was 90.3%, and this value was 5.4 times higher than that of the uncatalyzed ozonation (16.8%). The quinoline mineralization followed a pseudo first-order kinetics with all the catalysts. The rate constant for the mineralization of quinoline by ozonation in the presence of CuFe2O4/SEP was 0.0885 min-1, which was 16.7 times higher than that in ozone alone (0.0053 min-1). Radical scavenging tests revealed that hydroxyl radical (OH) and superoxide radical (O2-) were the reactive oxygen species (ROS) in the quinoline degradation. In the presence of CuFe2O4/SEP, ozone and hydrogen peroxide were rapidly converted into the ROS. Although neutral and alkaline pH were more beneficial for the quinoline mineralization, CuFe2O4/SEP exhibited significant catalytic activity even under acidic conditions. Meanwhile, five-cycle successive tests suggested that CuFe2O4/SEP was recyclable and hence, stable. Furthermore, the feasibility of the catalytic ozonation for the treatment of biologically treated coking wastewater was evaluated. The catalytic ozonation resulted in 57.81% total organic carbon removal efficiency at 60 min, which was 2.9 times higher than that in the uncatalyzed ozonation (19.99%).
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