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  • Title: Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides.
    Author: Yu W, Chen L, Tao J, Wang T, Fu J.
    Journal: Chem Commun (Camb); 2019 May 21; 55(42):5918-5921. PubMed ID: 31045192.
    Abstract:
    A novel reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides has been realized via photoredox/nickel dual catalysis to produce vinyl arene derivatives bearing all-carbon quaternary centers with excellent E-selectivity. A stoichiometric metal reductant could be avoided by employing commercially available N,N,N',N'-tetramethylethylenediamine (TMEDA) as the terminal reductant.
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