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  • Title: Determination of Parent and Oxygenated Polycyclic Aromatic Hydrocarbons (PAHs) in Waste Cooking Oil and Oil Deodorizer Distillate by GC-QQQ-MS.
    Author: Teng C, Wu S, Sun Y, Gong G.
    Journal: J AOAC Int; 2019 Nov 01; 102(6):1884-1891. PubMed ID: 31208496.
    Abstract:
    Background: Polycyclic aromatic hydrocarbons (PAHs) and oxygenated PAHs (OPAHs) are classes of contaminants that are present in the environment and food. They pose a great threat to human health because of their carcinogenicity and mutagenicity. Very few studies have focused on their concentration in waste cooking oil (WCO) and oil deodorizer distillate (ODD). Objective: This study aimed (1) to design a reliable method to determine 16 PAHs and 4 OPAHs in both WCO and ODD and (2) to determine and analyze PAH and OPAH concentrations in actual samples to provide references for further research. Method: The PAH determination approach included double liquid-liquid extraction, double solid-phase extraction, and GC-triple quadrupole tandem MS determination. Oxidation indices were determined by titrimetry. Results: The method reached good linearity (R² > 0.99) and an acceptable recovery rate (55.01-126.16% for WCO and 57.48-128.97% for ODD). Ten WCO and five ODD samples were determined, and the total concentration of 16 PAHs varied from 16.34 to 239.01 and 101.08 to 198.04 μg/kg in WCO and ODD, respectively. Among the 16 PAHs, three-ring PAHs typically contributed the most. It was also found that the acid value has a strong correlation with the concentration of OPAHs, probably because of the contribution of free fatty acids to OPAH formation. Conclusions: The proposed method was effective in the analysis of PAHs and OPAHs in WCO and ODD.
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