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  • Title: In situ growth of ZIF-8 nanoparticles on chitosan to form the hybrid nanocomposites for high-efficiency removal of Congo Red.
    Author: Wang Y, Dai X, Zhan Y, Ding X, Wang M, Wang X.
    Journal: Int J Biol Macromol; 2019 Sep 15; 137():77-86. PubMed ID: 31254578.
    Abstract:
    The zeolitic imidazole framework (ZIF-8) dotted chitosan (CS) nanocomposites (ZIF-8@CS) were fabricated via in-situ growth method. The morphology, structure and chemical state of ZIF-8@CS were investigated by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform IR spectroscopy (FTIR) and X-ray diffraction (XRD). The adsorption behavior of ZIF-8@CS composites on Congo Red (CR) in aqueous solution was systematically investigated. The adsorption isotherm data showed that the adsorption of CR by ZIF-8@CS was single-layer adsorption, which was consistent with the Langmuir isotherm model. The maximum adsorption capacity of ZIF-8@CS was 922 mg/g. The kinetics parameters were in accord with pseudo-second-order equation, which implied that the adsorption rate was mainly controlled by the chemisorption mechanism. The removal of CR was attributed to the participation of hydrogen bonds, electrostatic interactions, π-π conjugation and zinc coordination effects.
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