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  • Title: Enantioselective Diels-Alder reaction of anthracene by chiral tritylium catalysis.
    Author: Zhang Q, Lv J, Luo S.
    Journal: Beilstein J Org Chem; 2019; 15():1304-1312. PubMed ID: 31293679.
    Abstract:
    The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantioselective Diels-Alder reaction of anthracene.
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