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  • Title: Reductive debromination of decabromodiphenyl ether by iron sulfide-coated nanoscale zerovalent iron: mechanistic insights from Fe(II) dissolution and solvent kinetic isotope effects.
    Author: Wei X, Yin H, Peng H, Chen R, Lu G, Dang Z.
    Journal: Environ Pollut; 2019 Oct; 253():161-170. PubMed ID: 31306823.
    Abstract:
    The mechanism that iron sulfide-coated nanoscale zero valent iron (S-nZVI) has better reduction activity towards organic pollutants than nanoscale zero-valent iron (nZVI) has long been debated. In this work, a systematic study was investigated to compare differences of main influences, BDE-209 degradation pathway, degradation kinetics and reduction mechanism of BDE-209 between nZVI and S-nZVI systems. The observed transformation rate of BDE-209 (kobs) by S-nZVI was 58.3 and 7.1 times greater than that by S2- and nZVI, respectively. The valence change of Fe and S on S-nZVI surface before and after BDE-209 degradation process based on XPS characterization confirmed that both Fe0 and iron sulfide were the reduction entity of the surface-mediated reaction. The presence of tetrahydrofuran (THF) promoted the surface contact of BDE-209 with S-nZVI, thus accelerating the BDE-209 degradation process. Compared with nZVI, the iron sulfide coated on the Fe0 core surface could not only greatly reduce unnecessary electron loss via Fe0 corrosion with water, but also accelerate the transmission of electrons from Fe0 core to organic pollutants according to Fe(II) dissolution and solvent kinetic isotope effects investigations. These findings help to clarify the synergistic degradation mechanism between Fe0 core and iron sulfide shell layer.
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