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  • Title: Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides.
    Author: Wang X, Wang Z, Nishihara Y.
    Journal: Chem Commun (Camb); 2019 Aug 29; 55(71):10507-10510. PubMed ID: 31407738.
    Abstract:
    Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon-fluorine bond cleavage and carbon-silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.
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