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  • Title: Empowering Transition-Metal-Free Cascade Protocol for the Green Synthesis of Biaryls and Alkynes.
    Author: Walia PK, Kumar M, Bhalla V.
    Journal: ACS Omega; 2018 Feb 28; 3(2):1983-1990. PubMed ID: 31458507.
    Abstract:
    The work being presented in this paper demonstrates the simple and efficient "transition-metal-free" and "light-mediated" synthetic protocol for the synthesis of aryl iodides/biaryls/alkynes from aryl bromides. Under ultraviolet irradiation and in basic aqueous media, aryl bromides undergo transformation into aryl iodides which efficiently couple via a cascade reaction with a wide range of terminal alkynes/unactivated arenes to generate target molecules under green conditions.
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