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  • Title: Magnetic Contrast at Spin-Flip Excitations: An Advanced X-Ray Spectroscopy Tool to Study Magnetic-Ordering.
    Author: Elnaggar H, Wang RP, Lafuerza S, Paris E, Tseng Y, McNally D, Komarek A, Haverkort M, Sikora M, Schmitt T, de Groot FMF.
    Journal: ACS Appl Mater Interfaces; 2019 Oct 02; 11(39):36213-36220. PubMed ID: 31495171.
    Abstract:
    The determination of the local orientation and magnitude of the magnetization in spin textures plays a pivotal role in understanding and harnessing magnetic properties for technological applications. Here, we show that by employing the polarization dependence of resonant inelastic X-ray scattering (RIXS), we can directly probe the spin ordering with chemical and site selectivity. Applied on the prototypical ferrimagnetic mixed-valence system, magnetite ([Fe3+]A[Fe3+,Fe2+]BO4), we can distinguish spin-flip excitations at the A and B antiferromagnetically coupled Fe3+ sublattices and quantify the exchange field. Furthermore, it is possible to determine the orbital contribution to the magnetic moment from detailed angular dependence measurements. RIXS dichroism measurements performed at spin-flip excitations with nanometer spatial resolution will offer a powerful mapping contrast suitable for the characterization of magnetic ordering at interfaces and engineered spin textures.
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