These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Synthesis of Colloidal Blue-Emitting InP/ZnS Core/Shell Quantum Dots with the Assistance of Copper Cations.
    Author: Huang F, Bi C, Guo R, Zheng C, Ning J, Tian J.
    Journal: J Phys Chem Lett; 2019 Nov 07; 10(21):6720-6726. PubMed ID: 31549508.
    Abstract:
    Colloidal InP quantum dots (QDs) have been considered as one of the most promising candidates for display and biolabeling applications because they are intrinsically toxicity-free and exhibit high photoluminescence. On account of the uncontrollable nucleation and growth during the synthesis of InP, obtaining high-quality blue-emitting InP QDs with uniform size distribution remains a challenge. Herein, we employ a novel synthetic approach for producing blue-emitting InP/ZnS core/shell QDs with the assistance of copper cations. The studies reveal that the copper ions could combine with phosphorus precursor to form hexagonal Cu3-xP nanocrystals, which competed with the nucleation process of InP QDs, resulting in the smaller sized InP QDs with blue photoluminescence emission. After the passivation of InP QDs with the ZnS shell, the synthesized InP/ZnS core/shell QDs present bright blue emission (∼425 nm) with a photoluminescence quantum yield of ∼25%, which is the shortest wavelength emission for InP QDs to date. This research provides a new way to synthesize ultrasmall semiconductor nanocrystals.
    [Abstract] [Full Text] [Related] [New Search]