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  • Title: Novel Hierarchical Fe(III)-Doped Cu-MOFs With Enhanced Adsorption of Benzene Vapor.
    Author: Sun X, Gu X, Xu W, Chen WJ, Xia Q, Pan X, Zhao X, Li Y, Wu QH.
    Journal: Front Chem; 2019; 7():652. PubMed ID: 31612128.
    Abstract:
    New hierarchical Fe(III)-doped Cu-MOFs (Fe-HK) were developed via introduction of Fe3+ ions during HKUST-1 synthesis. The obtained products were characterized by N2 adsorption, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, FTIR spectroscopy, and thermal analysis. The adsorption isotherms and kinetics of benzene vapor were measured and consecutive adsorption-desorption cycles were performed. It was found that the hierarchical-pore Fe-HK-2 exhibited optimal textural properties with high BET surface area of 1,707 m2/g and total pore volume of 0.93 cm3/g, which were higher than those of the unmodified HKUST-1. Significantly, the hierarchical-pore Fe-HK-2 possessed outstanding benzene adsorption capacity, which was 1.5 times greater than the value on HKUST-1. Benzene diffusivity of Fe-HK-2 was 1.7 times faster than that of parent HKUST-1. Furthermore, the benzene adsorption on Fe-HK-2 was highly reversible. The hierarchical-pore Fe-HK-2 with high porosity, outstanding adsorption capacity, enhanced diffusion rate, and excellent reversibility might be an attractive candidate for VOCs adsorption. This may offer a simple and effective strategy to synthesize hierarchical-pore MOFs by doping with other metal ions.
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