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  • Title: Development and application of fluorescence sensor and test strip based on molecularly imprinted quantum dots for the selective and sensitive detection of propanil in fish and seawater samples.
    Author: Liu CX, Zhao J, Zhang RR, Zhang ZM, Xu JJ, Sun AL, Chen J, Shi XZ.
    Journal: J Hazard Mater; 2020 May 05; 389():121884. PubMed ID: 31879102.
    Abstract:
    Molecularly imprinted quantum dots (MIP-QDs) were successfully synthesized via reversed-phase microemulsion and used as the specific recognition element and signal probe of a fluorescence sensor or test strip to achieve the highly sensitive detection of propanil. The physical-chemical characteristics and excellent selectivity of MIP-QDs were elucidated. Under optimized parameters, the MIP-QDs had good linearity at the propanil concentration range of 1.0 μg/L to 20.0 × 103 μg/L by fluorescence quenching. The developed MIP-QD-based fluorescence sensor showed good recoveries ranging from 87.2 % to 112.2 %, and the relative standard deviation was below 6.0 % for the fish and seawater samples. In addition, the limits of detection (LODs) for fish and seawater were 0.42 μg/kg and 0.38 μg/L, respectively. The fluorescence test strip developed on the basis of the MIP-QDs also displayed satisfactory recoveries of 90.1 %-111.1 %, and the LOD for propanil in the seawater sample was 0.6 μg/L. The proposed fluorescence sensor and test strip were successfully used in propanil determination in environment and aquatic products.
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